Optimizing And Comparative of Polymer-45S5BG and Polymer- HA Coating by Electrophoretic Deposition (EPD)

Nour Abdulkareem Rasheed; Makarim  H. Abdulkareem; Iman  Adnan Anoon

doi:10.24237/djes.2021.14402

Authors

Nour Abdulkareem Rasheed
noorkareem772@yahoo.com
Department of Production and Metallurgy Engineering, University of Technology, Baghdad – Iraq
Makarim H. Abdulkareem Department of Production and Metallurgy Engineering, University of Technology, Baghdad – Iraq
Iman Adnan Anoon Department of Production and Metallurgy Engineering, University of Technology, Baghdad – Iraq

Keywords:

Electrophoretic deposition,, Gelatin, Chitosan, 45S5BG, Taguchi approach

Abstract

In this study, two systems of bio-ceramic coating (45S5 bioactive glass and hydroxyapatite) were used in order to compare between them for biomedical applications. Each system consists from two layers of coating done by electrophoretic deposition (EPD) technique on 316L stainless steel material as substrate. Two types of biopolymer were used (Chitosan with Gelatin) as first layer of coating. Taguchi approach with L9 array was used in order to choose the best conditions (concentrations, voltage and time) for coating layers. Each system consists of two layer (biopolymer (first layer) and bioceramic (second layer)) materials. The optimum parameters for first layer of biopolymer was (3g/L concentration, 20 voltage and 3 minute) while optimum parameters for second layer of bioceramic group (6g/L concentration, 30 voltage and 1 minute) for 45S5 BG system and (6g/L concentration, 40 voltage and 1 minute) for HA system. Zeta potential test were employed to measure suspensions stability. The tape test method was used to evaluate the adhesion between substrate and coating layers, the results show that the percentage of removal area for optimum coating layer (biopolymer, 45S5 BG and HA 8.06%, 10.668%, 6.01% subsequently). XRD inspection was used for identify the phases of coating layers. The Cyclic polarization test was used for evaluation of pitting corrosion resistance, the results show all layers gives good corrosion resistance but 45S5BG system gives the best corrosion resistance when compared with HA system.

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