Rheological Behavior of Isothermal Cured Epoxy/1,4-Diaminobenzene Systems

https://doi.org/10.24237/djes.2018.11107

Authors

  • Muataz H. Ismael Department of Chemical Engineering, University of Daiyla, Iraq
  • Salah N. Farhan Department of Chemical Engineering, University of Daiyla, Iraq
  • Ayad Dari Jaafar Department of Chemical Engineering, University of Technology, Iraq

Keywords:

Rheological, Curing agent system, Epoxy system, Curing temperature

Abstract

A novel curing agent (1,4-diaminobenzene) was used to enhance behavior of the epoxy resin system. The effect of the curing agent content (12 to 21 wt%) subjected to the isothermal curing temperatures at 80 °C to 110 °C were performed. Results indicate that the gel time was effected slightly on the viscosity when the curing temperature was higher than 90 °C and curing material consist over from 18wt %. These results explain that reaction rates caused by higher curing temperature.

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References

Dispenza, C.; Carter, J.; McGrail, P.; Spadaro, G. Cure behaviour of epoxy resin

matrices for carbon fibre composites. Polym. Int. 1999, 48, 1229–1236.

Zhou, G.; Movva, S.; Lee, L.J. Nanoclay and long-fiberreinforced composites based on epoxy and alternative to vinyl ester resins. J. Appl. Polym. Sci. 2010, 115, 665–673.

Xu, Y.; Hoa, S.V. Mechanical properties of carbon fiber reinforced epoxy/clay nanocomposites. Compos. Sci. Technol. 2008, 68, 854–861.

Chatterjee, A.; Gillespie, J.W., Jr. Room temperature-curable VARTM epoxy resins: Promising

Ayad D. Jaafar," Degradation of Organic Dyes using Photo-CatalyticTechnique",Al-Qadisiyah journal for Eng. Science,vol.8,No. 2,2015.

Green, K.J.; Dean, D.R.; Vaidya, U.K.; Nyairo, E. Multiscale fiber reinforced composites based on a carbon nanofiber/epoxy nanophased polymer matrix:Synthesis, mechanical, and thermomechanical behavior. Compos. Part A 2009, 40, 1470–1475.

Wen, X.F.; Wang, X.F.; Cai, Z.Q.; Pi, P.H.; Cheng, J.; Yang, Z.R. Cure kinetics and chemorheological behavior of a wind epoxy resin system and its viscoelastic properties reinforced by glass fiber matt with process of vacuum assisted resin transfer molding. High Perform. Polym. 2011, 23, 477–484.

Halley, P.J.; Mackay, M.E. Chemorheology of thermosets—An overview. Polym. Eng. Sci. 1996, 36, 593–609.

Mounif, E.; Bellenger,V.; Mazabraud, P.; Nony, F.; Tcharkhtchi, A. Chemorheological study of DGEBA/IPD system for reactive rotational molding (RRM). J. Appl. Polym. Sci. 2010, 116, 969–976.

Bashar jawad , Najat J. “ Study of the Cure Reaction of Epoxy Resin Diglycidyl Ether of Bisphenol-A (DGEBA) with Meta- Phenylene Diamine” Eng. & Tech. Journal, Vol.31, Part (A), No.9, 2013 .`

Published

2018-03-01

How to Cite

[1]
Muataz H. Ismael, S. N. Farhan, and Ayad Dari Jaafar, “Rheological Behavior of Isothermal Cured Epoxy/1,4-Diaminobenzene Systems”, DJES, vol. 11, no. 1, pp. 38 –, Mar. 2018.