Characteristics and Morphological Studies of Nd Doped Titanium Thin Film Coating on SS 316L by DC Sputtering

Rana  A. Anaee; Hiba  A. Abdullah

doi:10.24237/djes.2022.15303

Authors

Rana A. Anaee
dr.rana_afif@yahoo.com
Department of Materials Engineering, University of Technology, Baghdad, Iraq
Hiba A. Abdullah Department of Materials Engineering, University of Technology, Baghdad, Iraq

Keywords:

Nd, Titanium coating, Bioimplant, DC sputtering, SS 316L

Abstract

Nd doped Titanium coating was applied on stainless steel 316L by DC sputtering method to investigate the corrosion behavior in simulated body fluid at 37°C. The characterization of coated surface was done by XRD analysis that shows the incorporation of coating peaks within peaks of substrate (SS 316L), SEM/EDS also used to identify the structure and elemental composition of coating layer and the results indicated the formation of titanium carbide with neodymium particles which distributed on the titanium thin film and the EDS analysis showed the presence of Ti, Nd, O and high percent of C. AFM analysis indicated the increasing in surface roughness from 52.20 nm to 176.7 nm after coating with more valleys and peaks in two and three dimensions images, as well as more resistant for wear after coating from Abbott-Firestone results. The results of corrosion measurement showed the more positive corrosion potential for coated surface and decreasing in corrosion current density to obtain protection efficiency equal to 97.11% due to ability of the coating layer to isolate the substrate from corrosive environment.

Downloads

Download data is not yet available.

References

S. Sedira, S. Achour, A. Avci, V. Eskizeybek, “Physical deposition of carbon doped titanium nitride film by DC magnetron sputtering for metallic implant coating use”, Applied Surface Science, vol. 295, pp. 81-85, 2014. DOI: https://doi.org/10.1016/j.apsusc.2014.01.010

O. A. Fouada, R.A. Geioushy, S.M. El-Sheikh, M.H. Khedr, I.A. Ibrahim, “Metalorganic chemical vapor deposition of Ti–O–C–N thin films using TBOT as a promising precursor”, Journal of Alloys and Compounds, vol. 509, pp. 6090-6095, 2011. DOI: https://doi.org/10.1016/j.jallcom.2011.03.030

L. Fieandt, K. Johansson, E. Lindahl, T. Larsson, M. Boman, D. Rehnlund, “Corrosion properties of CVD grown Ti(C, N) coatings in 3.5 wt-% NaCl environment”, Corrosion Engineering, Science and Technology, vol. 53, pp. 316-320, 2018. DOI: https://doi.org/10.1080/1478422X.2018.1467150

B. Burnat, P. Olejarz, D. Batory, M. Cichomski, M. Kaminska, D. Bociag, “Titanium dioxide coatings doubly-doped with Ca and Ag ions as corrosion resistant, Biocompatible, and Bioactive Materials for Medical Applications”, Coatings, vol. 10, pp.169, 2020. DOI: https://doi.org/10.3390/coatings10020169

R. Anaee, A. Abdulkarim, M. Mathew, H. Jedy, “The effect of Nb2O5/Ni coatings on the microstructural and corrosion behavior on carbon steel for marine application”, Journal of Bio- and Tribo-Corrosion, vol. 7, pp. 1, 2021. DOI: https://doi.org/10.1007/s40735-020-00440-0

H. Abdulaah, A. Al-Ghaban, R. Anaee, “Deposition and characterization of Ca3Ce (PO4)3 phase in coating to protect stainless steel 316L”, AIP Conference Proceedings, 2372, 040004, 2021. DOI: https://doi.org/10.1063/5.0067094

H. Abdullah, A. Al-Ghaban, R. Anaee, “Deposition of CeO2/TCP thin film on stainless steel 316 L by RF sputtering”, Engineering and Technology Journal, vol. 39, pp. 625-631, 2021. DOI: https://doi.org/10.30684/etj.2021.168140

N. Najm, A. Ataiwi, R. Anaee, “Annealing and coating influence on the mechanical properties, microstructure, and corrosion properties of biodegradable Mg alloy (AZ91)”, Journal of Bio- and Tribo-Corrosion, vol. 8, pp. 64, 2022. DOI: https://doi.org/10.1007/s40735-022-00662-4

K. Shaha, Y. Pei, C. Chen, A. Turkin, D. Vainshtein, J. De Hosson, “On the dynamic roughening transition in nanocomposite film growth”, Applied Physics Letters, vol. 95, pp. 223102, 2009. DOI: https://doi.org/10.1063/1.3262952

A. Shamsikasmaei, M. Sohrabi, Sh. Dehaghi, H. Ghasemi, “Using the Taguchi optimization method for a Di-Azo dye by UV/Nd-TiO2 and a fixed bed system”, Fresenius Environmental Bulletin, vol. 22, 2013.

W. Dong, “Comprehensive study of parameters for characterising three-dimensional surface topography. III: Parameters for characterising amplitude and some functional properties”, Wear, vol. 178, pp. 29-43, 1994. DOI: https://doi.org/10.1016/0043-1648(94)90127-9

Z. Stamboliska, M. Kuzinovski, “Analysis and Mathematical Interpretation of Parameters That Describe the Microstereometry of Machined Surfaces” 3th Inter. Conf. of Tribology, I, 1999, pp. 21-28.

P. Kjeldsteen, “Wear resistance of PM materials and its dependency on surface topography”, Procs of Powder Metallurgy World Congress, vol. 1, pp. 657-660, 1994.

P. Kjeldsteen, “Tribological investigations of P/M Stainless steels mixed with HCX23 against Al2O3 & SiC”, Danfoss Research Report MUP2 (1997).

E. Yaqo, R. Anaee, M. Abdulmajeed, I. Tomi, M. Kadhim, “Electrochemical, morphological and theoretical studies of an oxadiazole derivative as an anti-corrosive agent for kerosene reservoirs in Iraqi refineries”, Chemical Papers, vol. 74, pp. 1739-1757, 2020. DOI: https://doi.org/10.1007/s11696-019-01022-2

N. Najm, A. Ataiwi, R. Anaee, “Effect of indium coating on corrosion behavior of AZ31 Mg alloy by DC sputtering”, Materials Today: Proceedings, vol. 62, pp. 4551-4555, 2022. DOI: https://doi.org/10.1016/j.matpr.2022.05.241

H. Abdullah, R. Adnan, R. Anaee, “Deposition of CaO to protect carbon steel by electrophoretic method”, Materials Today: Proceedings, vol. 26, pp. 4556-4561, 2022. DOI: https://doi.org/10.1016/j.matpr.2022.05.246